Multilayer Polyimide Aerogel Thermal Protection Film with Silicone PSA AZ-TPS PI 100

AZ-TPS PI 100 is a 240 micron (9.5 mil) multilayer thermal protection film built around a 165 micron (6.5 mil) AeroZero® polyimide aerogel core, faced with polyimide films and silicone pressure-sensitive adhesive (PSA) layers, delivering a thermal conductivity of 0.046 W/m·K at 25°C. The silicone PSA bonds to stainless steel, aluminum, glass, and polymer substrates, reaching full adhesion strength after a 3-day room-temperature dwell, and the construction carries a UL94 VTM-0 flame rating. The film remains flexible and RF transparent, suiting complex, contoured part geometries across Aerospace, Defense, and Electronics applications.

Key Properties

  • Thermal Conductivity (25°C): 0.046 W/m·K
  • Tensile Strength: 15 MPa (2 ksi)
  • Tensile Elongation at Break: 8%
  • Adhesive Strength (180° peel, 3-day RT dwell, AZ film on 2 mil Al foil): >200 N/m (1.1 lbf/in)
  • Glass Transition / Decomposition Temperature: 305°C (580°F) Tg / 410°C (770°F) decomposition (10 wt% loss)
  • Thickness: 240 µm (9.5 mil)

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    Physical Properties

    Property Value Test Method
    Thickness, µm (mil) 240 (9.5) In-House Method
    Density, g/cm³ 0.58 In-House Method

    Mechanical Properties

    Property Value Test Method
    Tensile Strength, MPa (ksi) 15 (2) ASTM D882-12
    Young’s Modulus, MPa (ksi) 450 (65) ASTM D882-12
    Tensile Elongation at Break, % 8 ASTM D882-12

    Thermal Properties

    Property Value Test Method
    Thermal Conductivity (25°C), W/m·K 0.046 ASTM C518-10
    Specific Heat Capacity (25°C), J/g·°C 1.22 ASTM C1784-20
    IR Emissivity (Polyimide Surface) 0.77 ASTM E408-13
    Glass Transition Temp (AZ Tg, DMA), °C (°F) 305 (580) ASTM E1640-13
    Decomposition Temp (10 wt% loss, TGA), °C (°F) 410 (770) ASTM 2550-17

    Adhesion Properties

    Property Value Test Method
    Adhesive Strength: 180° peel/3 day-RT dwell time AZ film on 50.8 micron (2 mil) Al Foil, N/m (lbf/in) >200 (1.1) ASTM D3330
    Adhesive Type Silicone

    Flame & Fire Performance

    Property Value Test Method
    UL Flammability Rating VTM-0 UL94 VTM0

    Construction

    Property Value Test Method
    Layer 1 — Polyimide (PI) 25.4 micron (1 mil)
    Layer 2 — Silicone Adhesive (PSA) 25.4 micron (1 mil)
    Layer 3 — AeroZero (AZ) 165 micron (6.5 mil)
    Layer 4 — Silicone Adhesive (PSA) 25.4 micron (1 mil)

    Compliance

    • UL94 VTM-0 — Compliant (UL Flammability Rating)
    Standard Thicknesses:240 µm (9.5 mil)
    Standard Colors:Natural / As Manufactured
    Supply Formats:Sheet stock, Slit rolls, Precision die-cut components, Kiss-cut parts, Laminated constructions, Supplied with peel-away release liner
    Misc Notes:Custom dimensions and converted formats available based on application requirements and production volume.
    • Thermal barrier protection for aerospace structures and components
    • Thermal shielding for defense systems and platforms
    • Thermal protection for electronic enclosures and devices
    • RF-transparent thermal barriers for antenna and sensor housings
    • Thermal protection film for complex, contoured part geometries

    Common industries: Aerospace, Defense, Electronics.

    AZ-TPS PI 100 is a multilayer, adhesive-backed thermal protection film from Blueshift Materials’ AeroZero® Thermal Protection Systems product line. The construction pairs a 165 micron (6.5 mil) AeroZero® polyimide aerogel core with 25.4 micron (1 mil) polyimide face films and 25.4 micron (1 mil) silicone pressure-sensitive adhesive layers on both sides, for a total thickness of 240 micron (9.5 mil). Its primary performance advantage is a low thermal conductivity of 0.046 W/m·K combined with an ultra-thin, lightweight, flexible format that allows it to be applied directly to complex, contoured part geometries as a permanent, self-adhered thermal barrier.

    The engineering-grade silicone PSA bonds to stainless steel, aluminum, glass, and polymer substrates such as polyimides, polyether ketones, polyurethanes, and polyesters, reaching optimal adhesion after a 3-day room-temperature dwell (minimum 24 hours at 10°C/50°F), with a peel-away release liner for straightforward application. The film carries a UL94 VTM-0 flame retardant rating and is RF transparent, making it suitable for use on or near antenna and sensor housings where signal transparency is required.

    AZ-TPS PI 100 is intended for thermal barrier and protection applications across the Aerospace, Defense, and Electronics industries. Compliant with UL94 VTM-0.

    What differentiates AZ-TPS PI 100 from other thermal protection film constructions?

    AZ-TPS PI 100 combines a 165 micron (6.5 mil) AeroZero® polyimide aerogel core with polyimide face films and silicone PSA layers on both sides in a total thickness of just 240 micron (9.5 mil). This ultra-thin, lightweight, flexible construction is self-adhering — bonding permanently to stainless steel, aluminum, glass, and a range of polymer substrates without additional fasteners or hardware — while remaining RF transparent and UL94 VTM-0 flame rated.

    Why does thermal conductivity matter in material selection for AZ-TPS PI 100?

    As a thermal barrier film, AZ-TPS PI 100's primary function is to isolate parts from heat. Its thermal conductivity of 0.046 W/m·K at 25°C allows it to provide effective thermal insulation in an ultra-thin, low-weight film format, avoiding the bulk and added weight of thicker traditional insulation while still protecting components in demanding thermal environments.

    What is the temperature range for AZ-TPS PI 100?

    The TDS lists a glass transition temperature (AZ Tg, DMA) of 305°C (580°F) and a decomposition temperature (10 wt% loss, TGA) of 410°C (770°F). The silicone PSA requires a minimum application temperature of 10°C (50°F) and reaches optimal adhesion after a 3-day room-temperature dwell.

    Is AZ-TPS PI 100 suitable for flame-rated environments?

    Yes. AZ-TPS PI 100 carries a UL94 VTM-0 flammability rating as listed on the manufacturer's TDS.

    How should AZ-TPS PI 100 be specified?

    Specify grade (AZ-TPS PI 100), thickness, adhesive/liner configuration, bond surface/substrate compatibility, compliance requirements, dimensional tolerances, and finished format.

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